Raman Evidences for Phase Transition of Sodium Perchlorate at High Pressure

HE Yunhong; TIAN Yu; ZHAO Huifang; JIANG Feng; TAN Dayong; XIAO Wansheng

doi:10.11858/gywlxb.20180543

Volume 32 Issue 4

Apr 2018

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Chinese Journal of High Pressure Physics > 2018 > 32(4): 041201.

HE Yunhong, TIAN Yu, ZHAO Huifang, JIANG Feng, TAN Dayong, XIAO Wansheng. Raman Evidences for Phase Transition of Sodium Perchlorate at High Pressure[J]. Chinese Journal of High Pressure Physics, 2018, 32(4): 041201. doi: 10.11858/gywlxb.20180543

Citation:

HE Yunhong, TIAN Yu, ZHAO Huifang, JIANG Feng, TAN Dayong, XIAO Wansheng. Raman Evidences for Phase Transition of Sodium Perchlorate at High Pressure[J]. Chinese Journal of High Pressure Physics, 2018, 32(4): 041201. doi: 10.11858/gywlxb.20180543

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Raman Evidences for Phase Transition of Sodium Perchlorate at High Pressure

doi: 10.11858/gywlxb.20180543

HE Yunhong^{1, 2, 3
,},
TIAN Yu^{1, 2, 3},
ZHAO Huifang^{1, 2, 3},
JIANG Feng^{1, 2, 3},
TAN Dayong^{1, 2},
XIAO Wansheng^{1, 2,*
,
,}

1.
CAS Key Laboratory of Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
2.
Key Lab of Guangdong Province for Mineral Physics and Materials, Guangzhou 510640, China
3.
University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 23 Apr 2018
Rev Recd Date: 11 Jun 2018

Abstract

Abstract

Using a diamond anvil cell apparatus, we investigated the sodium perchlorate (NaClO₄) by Raman spectroscopy at pressure up to 20 GPa, and calculated the Raman spectra of anhydrite-(Cmcm), monazite-(P2₁/n), AgMnO₄-(P2₁/n), and barite-type (Pnma) structures of NaClO₄ by density function theory.The experimental data show that anhydrite-type NaClO₄ undergoes a structural transition at about 4 GPa.A new peak at lower Raman frequencies (975 cm^-1) than that of the ClO₄^- internal mode ν₁ (A_g) of the NaClO₄ ambient phase was obviously observed at 4.4 GPa.At the same time, several peaks at the corresponding wave numbers of the ClO₄^- internal modes (ν₂、ν₃、ν₄) arise.The phase transition is completed at about 6.1 GPa, and remains stable up to 19.5 GPa.The high pressure structure can be recovered at about 3.1 GPa in decompression.By comparison with the calculated Raman spectral profiles (at 8.0 GPa) of three potential high pressure structures, we infer that the high pressure phase has a monoclinic monazite-type structure.The pressure-induced phase transition of NaClO₄ is consistent with the anhydrite-monazite phase transition found in CaSO₄ at about 2 GPa.However, our finding appears inconsistency with the previous observations that the anhydrite-type NaClO₄ transforms to AgMnO₄-type at about 2 GPa and furthermore to the barite-type structure at around 3 GPa.The previous results could probably be influenced by the moisture of the sample combining with the high temperature and high pressure conditions.It may bring more complicated changes by simultaneous high pressure and high temperature environments.The research progress contributes to the understanding of not only the relationship between volcanic activity and the widespread distribution of perchlorate on Mars, but also the changes and functions of chlorine element during the recycles of subduction and mantle plume in the Earth's deep interior.
- NaClO₄,
- high pressure,
- Raman spectrum,
- phase transition,
- Monazite-type structure

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References

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