| Citation: | SUN Liang, CHEN Zhongjing, XI Tao, YANG Xun, YAN Ji, YANG Jiamin, ZHAO Zongqing. Phase Diagram and Dynamic Transformation Pathways of Carbon under Extreme Compression[J]. Chinese Journal of High Pressure Physics, 2026, 40(9): 090108. doi: 10.11858/gywlxb.20261127 |
| [1] |
SUNDQVIST B. Carbon under pressure [J]. Physics Reports, 2021, 909: 1–73. doi: 10.1016/j.physrep.2020.12.007
|
| [2] |
SHANG Y C, LIU Z D, DONG J J, et al. Ultrahard bulk amorphous carbon from collapsed fullerene [J]. Nature, 2021, 599(7886): 599–604. doi: 10.1038/s41586-021-03882-9
|
| [3] |
HU Q Y, LI B S, GAO X, et al. Ultrasound elasticity of diamond at gigapascal pressures [J]. Proceedings of the National Academy of Sciences of the United States of America, 2021, 118(51): e2118490118. doi: 10.1073/pnas.2118490118
|
| [4] |
ROSS M. The ice layer in Uranus and Neptune—diamonds in the sky? [J]. Nature, 1981, 292(5822): 435–436. doi: 10.1038/292435a0
|
| [5] |
ABU-SHAWAREB H, ACREE R, ADAMS P, et al. Achievement of target gain larger than unity in an inertial fusion experiment [J]. Physical Review Letters, 2024, 132(6): 065102. doi: 10.1103/PhysRevLett.132.065102
|
| [6] |
YANG L X, LAU K C, ZENG Z D, et al. Synthesis of bulk hexagonal diamond [J]. Nature, 2025, 644(8076): 370–375. doi: 10.1038/s41586-025-09343-x
|
| [7] |
EGGERT J H, HICKS D G, CELLIERS P M, et al. Melting temperature of diamond at ultrahigh pressure [J]. Nature Physics, 2010, 6(1): 40–43. doi: 10.1038/nphys1438
|
| [8] |
FROST M, MCWILLIAMS R S, BYKOVA E, et al. Diamond precipitation dynamics from hydrocarbons at icy planet interior conditions [J]. Nature Astronomy, 2024, 8(2): 174–181. doi: 10.1038/s41550-023-02147-x
|
| [9] |
LAZICKI A, MCGONEGLE D, RYGG J R, et al. Metastability of diamond ramp-compressed to 2 terapascals [J]. Nature, 2021, 589(7843): 532–535. doi: 10.1038/s41586-020-03140-4
|
| [10] |
CORREA A A, BONEV S A, GALLI G. Carbon under extreme conditions: phase boundaries and electronic properties from first-principles theory [J]. Proceedings of the National Academy of Sciences of the United States of America, 2006, 103(5): 1204–1208. doi: 10.1073/pnas.0510489103
|
| [11] |
KRAUS D, RAVASIO A, GAUTHIER M, et al. Nanosecond formation of diamond and lonsdaleite by shock compression of graphite [J]. Nature Communications, 2016, 7(1): 10970. doi: 10.1038/ncomms10970
|
| [12] |
KRAUS D, VORBERGER J, PAK A, et al. Formation of diamonds in laser-compressed hydrocarbons at planetary interior conditions [J]. Nature Astronomy, 2017, 1(9): 606–611. doi: 10.1038/s41550-017-0219-9
|
| [13] |
HUBBARD W B, NELLIS W J, MITCHELL A C, et al. Interior structure of Neptune: comparison with Uranus [J]. Science, 1991, 253(5020): 648–651. doi: 10.1126/science.253.5020.648
|
| [14] |
MILLOT M, STERNE P A, EGGERT J H, et al. High-precision shock equation of state measurements for metallic fluid carbon between 15 and 20 Mbar [J]. Physics of Plasmas, 2020, 27(10): 102711. doi: 10.1063/5.0007304
|
| [15] |
BOEHLY T R, GONCHAROV V N, SEKA W, et al. Velocity and timing of multiple spherically converging shock waves in liquid deuterium [J]. Physical Review Letters, 2011, 106(19): 195005. doi: 10.1103/PhysRevLett.106.195005
|
| [16] |
GAFFNEY J A, HU S X, ARNAULT P, et al. A review of equation-of-state models for inertial confinement fusion materials [J]. High Energy Density Physics, 2018, 28: 7–24. doi: 10.1016/j.hedp.2018.08.001
|
| [17] |
CORREA A A, BENEDICT L X, YOUNG D A, et al. First-principles multiphase equation of state of carbon under extreme conditions [J]. Physical Review B, 2008, 78(2): 024101. doi: 10.1103/PhysRevB.78.024101
|
| [18] |
BENEDICT L X, DRIVER K P, HAMEL S, et al. Multiphase equation of state for carbon addressing high pressures and temperatures [J]. Physical Review B, 2014, 89(22): 224109. doi: 10.1103/PhysRevB.89.224109
|
| [19] |
MAO H K, CHEN X J, DING Y, et al. Solids, liquids, and gases under high pressure [J]. Reviews of Modern Physics, 2018, 90(1): 015007. doi: 10.1103/RevModPhys.90.015007
|
| [20] |
DUFFY T S, SMITH R F. Ultra-high pressure dynamic compression of geological materials [J]. Frontiers in Earth Science, 2019, 7: 23. doi: 10.3389/feart.2019.00023
|
| [21] |
SUN L, CHEN B, CHEN Z J, et al. Investigating phase dynamics of materials under laser-induced extreme conditions [J]. Matter and Radiation at Extremes, 2025, 10(6): 063002. doi: 10.1063/5.0274747
|
| [22] |
MA G C, ZHANG G M, SONG H Z, et al. The high pressure multiphase equation of state of carbon [J]. Journal of Physical Science and Application, 2018, 8(2): 11–16. doi: 10.17265/2159-5348/2018.02.002
|
| [23] |
BUNDY F P. Melting of graphite at very high pressure [J]. Journal of Chemical Physics, 1963, 38(3): 618–630. doi: 10.1063/1.1733715
|
| [24] |
AO T, KALITA P, BLADA C, et al. Exploring the high-pressure phases of carbon through X-ray diffraction of dynamic compression experiments on Sandia’s Z pulsed power facility [J]. Minerals, 2023, 13(9): 1203. doi: 10.3390/min13091203
|
| [25] |
KNUDSON M D, DESJARLAIS M P, DOLAN D H. Shock-wave exploration of the high-pressure phases of carbon [J]. Science, 2008, 322(5909): 1822–1825. doi: 10.1126/science.1165278
|
| [26] |
SUN L, LIU H, DUAN X X, et al. In situ XRD measurement for high-pressure iron in laser-driven off-Hugoniot state [J]. Minerals, 2024, 14(7): 715. doi: 10.3390/min14070715
|
| [27] |
CELLIERS P M, BRADLEY D K, COLLINS G W, et al. Line-imaging velocimeter for shock diagnostics at the OMEGA laser facility [J]. Review of Scientific Instruments, 2004, 75(11): 4916–4929. doi: 10.1063/1.1807008
|
| [28] |
CELLIERS P M, MILLOT M. Imaging velocity interferometer system for any reflector (VISAR) diagnostics for high energy density sciences [J]. Review of Scientific Instruments, 2023, 94(1): 011101. doi: 10.1063/5.0123439
|
| [29] |
BRYGOO S, MILLOT M, LOUBEYRE P, et al. Analysis of laser shock experiments on precompressed samples using a quartz reference and application to warm dense hydrogen and helium [J]. Journal of Applied Physics, 2015, 118(19): 195901. doi: 10.1063/1.4935295
|
| [30] |
WADAS M, BRYGOO S, LOUBEYRE P, et al. Shock compression of liquid helium to 360 GPa [J]. Physical Review Research, 2026, 8(1): 013335. doi: 10.1103/87r3-tgy1
|
| [31] |
MILLER J E, BOEHLY T R, MELCHIOR A, et al. Streaked optical pyrometer system for laser-driven shock-wave experiments on OMEGA [J]. Review of Scientific Instruments, 2007, 78(3): 034903. doi: 10.1063/1.2712189
|
| [32] |
YE Z X, SMITH R F, MILLOT M, et al. Shock equation of state experiments in MgO up to 1.5 TPa and the effects of optical depth on temperature determination [J]. Journal of Applied Physics, 2024, 136(10): 105904. doi: 10.1063/5.0226765
|
| [33] |
WICKS J K, SINGH S, MILLOT M, et al. B1-B2 transition in shock-compressed MgO [J]. Science Advances, 2024, 10(23): eadk0306. doi: 10.1126/sciadv.adk0306
|
| [34] |
PALEARI S, BATANI D, VINCI T, et al. A new target design for laser shock-compression studies of carbon reflectivity in the megabar regime [J]. The European Physical Journal D, 2013, 67(7): 136. doi: 10.1140/epjd/e2013-30630-8
|
| [35] |
RYGG J R, SMITH R F, LAZICKI A E, et al. X-ray diffraction at the National Ignition Facility [J]. Review of Scientific Instruments, 2020, 91(4): 043902. doi: 10.1063/1.5129698
|
| [36] |
LAZICKI A, RYGG J R, COPPARI F, et al. X-ray diffraction of solid tin to 1.2 TPa [J]. Physical Review Letters, 2015, 115(7): 075502. doi: 10.1103/PhysRevLett.115.075502
|
| [37] |
POLSIN D N, RYGG J R, BISHEL D T, et al. Multiframe X-ray diffraction on the OMEGA EP laser [J]. Review of Scientific Instruments, 2025, 96(6): 063510. doi: 10.1063/5.0260046
|
| [38] |
WERELLAPATHA K, PALMER N E, GORMAN M G, et al. Time-resolved X-ray diffraction diagnostic development for the National Ignition Facility [J]. Review of Scientific Instruments, 2024, 95(1): 013903. doi: 10.1063/5.0161343
|
| [39] |
PASCARELLI S, MCMAHON M, PÉPIN C, et al. Materials under extreme conditions using large X-ray facilities [J]. Nature Reviews Methods Primers, 2023, 3(1): 82. doi: 10.1038/s43586-023-00264-5
|
| [40] |
TURNEAURE S J, SHARMA S M, VOLZ T J, et al. Transformation of shock-compressed graphite to hexagonal diamond in nanoseconds [J]. Science Advances, 2017, 3(10): eaao3561. doi: 10.1126/sciadv.aao3561
|
| [41] |
ARMSTRONG M R, RADOUSKY H B, AUSTIN R A, et al. Highly ordered graphite (HOPG) to hexagonal diamond (lonsdaleite) phase transition observed on picosecond time scales using ultrafast X-ray diffraction [J]. Journal of Applied Physics, 2022, 132(5): 055901. doi: 10.1063/5.0085297
|
| [42] |
VOLZ T J, TURNEAURE S J, SHARMA S M, et al. Role of graphite crystal structure on the shock-induced formation of cubic and hexagonal diamond [J]. Physical Review B, 2020, 101(22): 224109. doi: 10.1103/PhysRevB.101.224109
|
| [43] |
CHEN G W, ZHU S C, XU L, et al. The transformation mechanism of graphite to hexagonal diamond under shock conditions [J]. JACS Au, 2024, 4(9): 3413–3420. doi: 10.1021/jacsau.4c00523
|
| [44] |
NÉMETH P, GARVIE L A J, AOKI T, et al. Lonsdaleite is faulted and twinned cubic diamond and does not exist as a discrete material [J]. Nature Communications, 2014, 5(1): 5447. doi: 10.1038/ncomms6447
|
| [45] |
NÉMETH P, LANCASTER H J, SALZMANN C G, et al. Shock-formed carbon materials with intergrown sp3- and sp2-bonded nanostructured units [J]. Proceedings of the National Academy of Sciences of the United States of America, 2022, 119(30): e2203672119. doi: 10.1073/pnas.2203672119
|
| [46] |
LAI S L, YANG X G, SHI J Y, et al. Bulk hexagonal diamond [J]. Nature, 2026, 651(8106): 621–625. doi: 10.1038/s41586-026-10212-4
|
| [47] |
TIAN Y J. Diamond: cubic to hexagonal [J]. Science China Materials, 2025, 68(8): 2988–2989. doi: 10.1007/s40843-025-3328-5
|
| [48] |
CHEN D S, CHEN G W, LV L, et al. General approach for synthesizing hexagonal diamond by heating post-graphite phases [J]. Nature Materials, 2025, 24(4): 513–518. doi: 10.1038/s41563-025-02126-9
|
| [49] |
HICKS D G, BOEHLY T R, CELLIERS P M, et al. High-precision measurements of the diamond Hugoniot in and above the melt region [J]. Physical Review B, 2008, 78(17): 174102. doi: 10.1103/PhysRevB.78.174102
|
| [50] |
KRAUS D, RIPS J, SCHÖRNER M, et al. The structure of liquid carbon elucidated by in situ X-ray diffraction [J]. Nature, 2025, 642(8067): 351–355. doi: 10.1038/s41586-025-09035-6
|
| [51] |
SHI J Y, LIANG Z X, WANG J J, et al. Double-shock compression pathways from diamond to BC8 carbon [J]. Physical Review Letters, 2023, 131(14): 146101. doi: 10.1103/PhysRevLett.131.146101
|
| [52] |
NGUYEN-CONG K, WILLMAN J T, GONZALEZ J M, et al. Extreme metastability of diamond and its transformation to BC8 post-diamond phase of carbon [J]. The Journal of Physical Chemistry Letters, 2024, 15(4): 1152–1160. doi: 10.1021/acs.jpclett.3c03044
|
| [53] |
MARTOŇÁK R, GALITSKIY S, TIPEEV A, et al. From diamond to BC8 to simple cubic and back: kinetic pathways to post-diamond carbon phases from metadynamics [J]. Physical Review B, 2026, 113(22): L220101. doi: 10.1103/djft-jvvn
|
| [54] |
CHEN B, ZENG Q Y, YU X X, et al. Three-step formation of diamonds in shock-compressed hydrocarbons: dissociation, species separation, and nucleation [J]. Matter and Radiation at Extremes, 2026, 11(1): 017603. doi: 10.1063/5.0273729
|
| [55] |
WANG Z Y, LUO X S, WANG Q C, et al. Advances in high-pressure materials discovery enabled by machine learning [J]. Matter and Radiation at Extremes, 2025, 10(3): 033801. doi: 10.1063/5.0255385
|
| [56] |
ZHANG H, YANG Y T, YANG W M, et al. Equation of state for boron nitride along the principal Hugoniot to 16 Mbar [J]. Matter and Radiation at Extremes, 2024, 9(5): 057403. doi: 10.1063/5.0206889
|