A-Site Ordered Quadruple Perovskite Oxides: Structures, Properties and Prospects

WANG Xiao; LIU Zhehong; LU Dabiao; PI Maocai; PAN Zhao; LONG Youwen

doi:10.11858/gywlxb.20230785

Volume 38 Issue 1

Feb 2024

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Chinese Journal of High Pressure Physics > 2024 > 38(1): 010101.

WANG Xiao, LIU Zhehong, LU Dabiao, PI Maocai, PAN Zhao, LONG Youwen. A-Site Ordered Quadruple Perovskite Oxides: Structures, Properties and Prospects[J]. Chinese Journal of High Pressure Physics, 2024, 38(1): 010101. doi: 10.11858/gywlxb.20230785

Citation:

WANG Xiao, LIU Zhehong, LU Dabiao, PI Maocai, PAN Zhao, LONG Youwen. A-Site Ordered Quadruple Perovskite Oxides: Structures, Properties and Prospects[J]. Chinese Journal of High Pressure Physics, 2024, 38(1): 010101. doi: 10.11858/gywlxb.20230785

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A-Site Ordered Quadruple Perovskite Oxides: Structures, Properties and Prospects

doi: 10.11858/gywlxb.20230785

WANG Xiao^1
,,
LIU Zhehong¹,
LU Dabiao^{1, 2},
PI Maocai^{1, 2},
PAN Zhao¹,
LONG Youwen^{1, 2, 3,*
,
,}

1.
Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
2.
School of Physical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
3.
Songshan Lake Materials Laboratory, Dongguan 523808, Guangdong, China

Received Date: 08 Nov 2023
Rev Recd Date: 15 Dec 2023

Available Online: 04 Feb 2024

Issue Publish Date: 05 Feb 2024

Abstract

Abstract

A-site ordered quadruple perovskite oxides with a formula as $\rm AA'_3 B^{\;}_4 O^{\;}_{12}$ exhibit multiple physical properties and superior performances, thus act as important subjects of current condensed matter physics and material science. Compared to the simple ABO₃ perovskite, in the A-site ordered quadruple perovskite three quarters of the A atoms are replaced by transition metal Aʹ, forming ordered A/Aʹ occupancy with a 1∶3 ratio. As a result, the electric and magnetic interactions such as Aʹ-Aʹ and Aʹ-B can occur, leading to novel phenomena and new physics. Here we focus on several representative A-site ordered quadruple perovskites, recall their researches, briefly introduce their structures, physical properties and inner mechanisms, and discuss the opportunities for both fundamental studies and potential applications.
- high-pressure synthesis,
- perovskite oxide,
- dielectricity,
- charge order,
- multiferroics,
- half metal

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References(120)

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A-Site Ordered Quadruple Perovskite Oxides: Structures, Properties and Prospects

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