Pressure-Induced Structural Phase Transition in Halide Perovskite CsGeBr<sub>3</sub>

QU Jia; WANG Yiming; WANG Xin; YANG Wenge

doi:10.11858/gywlxb.20230769

Volume 38 Issue 5

Sep 2024

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Chinese Journal of High Pressure Physics > 2024 > 38(5): 050102.

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QU Jia, WANG Yiming, WANG Xin, YANG Wenge. Pressure-Induced Structural Phase Transition in Halide Perovskite CsGeBr₃[J]. Chinese Journal of High Pressure Physics, 2024, 38(5): 050102. doi: 10.11858/gywlxb.20230769

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Pressure-Induced Structural Phase Transition in Halide Perovskite CsGeBr₃

doi: 10.11858/gywlxb.20230769

QU Jia^{1, 2
,},
WANG Yiming²,
WANG Xin^{1,*
,
,},
YANG Wenge^{2,*
,
,}

1.
State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012, Jilin, China
2.
Center for High Pressure Science and Technology Advanced Research, Shanghai 201203, China

Received Date: 25 Oct 2023
Rev Recd Date: 15 Dec 2023
Accepted Date: 25 Dec 2023

Available Online: 19 Jul 2024

Issue Publish Date: 29 Sep 2024

Abstract

Abstract

In recent years, pressure-induced physical properties of halide perovskites have attracted significant research interests due to their excellent optical and electronic properties. The study of the structural evolution of perovskite under compression is the foundation and key point of all physical property researches. In this paper, we systematically investigated the structural evolution of the all-inorganic halide perovskite CsGeBr₃ under compression using in situ high-pressure synchrotron X-ray diffraction, in situ high-pressure Raman spectroscopy, ultraviolet/visible/near-infrared spectrophotometry, and first-principles calculations. Our results show that CsGeBr₃ undergoes a reversible rhombohedral $R3m$ to cubic $Pm\overline{3}m$ structural phase transition at 1 GPa, and the cubic $Pm\overline{3}m$ phase maintains at higher pressures. This study provides important scientific basis for further exploration of the properties and applications of halide perovskites under compression.
- high pressure,
- CsGeBr₃,
- structural phase transition,
- halide perovskite

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References

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Pressure-Induced Structural Phase Transition in Halide Perovskite CsGeBr₃

doi: 10.11858/gywlxb.20230769

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Pressure-Induced Structural Phase Transition in Halide Perovskite CsGeBr₃