High-Pressure Raman Spectroscopy of hcp Metals

LIU Jingyi; TAO Yu; FAN Chunmei; WU Binbin; LEI Li

doi:10.11858/gywlxb.20220522

Volume 36 Issue 5

Oct 2022

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Chinese Journal of High Pressure Physics > 2022 > 36(5): 051102.

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LIU Jingyi, TAO Yu, FAN Chunmei, WU Binbin, LEI Li. High-Pressure Raman Spectroscopy of hcp Metals[J]. Chinese Journal of High Pressure Physics, 2022, 36(5): 051102. doi: 10.11858/gywlxb.20220522

Citation:

LIU Jingyi, TAO Yu, FAN Chunmei, WU Binbin, LEI Li. High-Pressure Raman Spectroscopy of hcp Metals[J]. Chinese Journal of High Pressure Physics, 2022, 36(5): 051102. doi: 10.11858/gywlxb.20220522

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High-Pressure Raman Spectroscopy of hcp Metals

doi: 10.11858/gywlxb.20220522

Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, Sichuan, China

Received Date: 26 Feb 2022
Rev Recd Date: 18 Mar 2022
Accepted Date: 18 Mar 2022

Available Online: 16 Sep 2022

Issue Publish Date: 11 Oct 2022

Abstract

Abstract

The lattice dynamics behavior of materials under high pressure can be studied by high-pressure Raman spectroscopy. However, Raman spectroscopic signal of metal samples at high pressure is difficult to obtain due to the fluorescence of the diamond in diamond anvil cell (DAC) and the strong reflection of the samples. In this work, we use DAC inclination scattering method to mitigate background noise. As a consequence, Raman spectroscopic signal of the hcp metal samples (Be, Re, Os) under high pressure have been achieved. In the case of Be, the pressure dependence of elastic constant C₄₄ is obtained by measuring the shear Raman mode E_2g at pressure up to 73 GPa. The proposed high-pressure Raman spectroscopy technique provides a new method to study bonding state, electronic structure, and phonon-electron coupling effects of metallic materials under high pressure.
- hcp metals,
- high pressure,
- Raman scattering,
- elastic properties

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References

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High-Pressure Raman Spectroscopy of hcp Metals

doi: 10.11858/gywlxb.20220522

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High-Pressure Raman Spectroscopy of hcp Metals

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