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Volume 36 Issue 5
Oct 2022
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Chinese Journal of High Pressure Physics  > 2022  >  36(5): 051102.
LIU Jingyi, TAO Yu, FAN Chunmei, WU Binbin, LEI Li. High-Pressure Raman Spectroscopy of hcp Metals[J]. Chinese Journal of High Pressure Physics, 2022, 36(5): 051102. doi: 10.11858/gywlxb.20220522
Citation: LIU Jingyi, TAO Yu, FAN Chunmei, WU Binbin, LEI Li. High-Pressure Raman Spectroscopy of hcp Metals[J]. Chinese Journal of High Pressure Physics, 2022, 36(5): 051102. doi: 10.11858/gywlxb.20220522
shu

High-Pressure Raman Spectroscopy of hcp Metals

doi: 10.11858/gywlxb.20220522

  • Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, Sichuan, China

  • Received Date: 26 Feb 2022
  • Rev Recd Date: 18 Mar 2022
  • Accepted Date: 18 Mar 2022
    • Available Online: 16 Sep 2022
  • Issue Publish Date: 11 Oct 2022
    Abstract
  • The lattice dynamics behavior of materials under high pressure can be studied by high-pressure Raman spectroscopy. However, Raman spectroscopic signal of metal samples at high pressure is difficult to obtain due to the fluorescence of the diamond in diamond anvil cell (DAC) and the strong reflection of the samples. In this work, we use DAC inclination scattering method to mitigate background noise. As a consequence, Raman spectroscopic signal of the hcp metal samples (Be, Re, Os) under high pressure have been achieved. In the case of Be, the pressure dependence of elastic constant C44 is obtained by measuring the shear Raman mode E2g at pressure up to 73 GPa. The proposed high-pressure Raman spectroscopy technique provides a new method to study bonding state, electronic structure, and phonon-electron coupling effects of metallic materials under high pressure.

     

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