Raman Scattering of Grossular-Andradite Solid Solution

WANG Yichuan

doi:10.11858/gywlxb.20200512

Volume 34 Issue 4

Jul 2020

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Chinese Journal of High Pressure Physics > 2020 > 34(4): 040101.

WANG Yichuan. Raman Scattering of Grossular-Andradite Solid Solution[J]. Chinese Journal of High Pressure Physics, 2020, 34(4): 040101. doi: 10.11858/gywlxb.20200512

Citation:

WANG Yichuan. Raman Scattering of Grossular-Andradite Solid Solution[J]. Chinese Journal of High Pressure Physics, 2020, 34(4): 040101. doi: 10.11858/gywlxb.20200512

WANG Yichuan. Raman Scattering of Grossular-Andradite Solid Solution[J]. Chinese Journal of High Pressure Physics, 2020, 34(4): 040101. doi: 10.11858/gywlxb.20200512

Citation:

WANG Yichuan. Raman Scattering of Grossular-Andradite Solid Solution[J]. Chinese Journal of High Pressure Physics, 2020, 34(4): 040101. doi: 10.11858/gywlxb.20200512

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Raman Scattering of Grossular-Andradite Solid Solution

doi: 10.11858/gywlxb.20200512

WANG Yichuan^{1, 2
,}

1.
School of Earth and Space Sciences, Peking University, Beijing 100871, China
2.
Key Laboratory of Orogenic Belts and Crustal Evolution, MOE, Peking University, Beijing 100871, China

Received Date: 20 Feb 2020
Rev Recd Date: 08 Mar 2020

Abstract

Abstract

The effects of Al³⁺-Fe³⁺ substitution on 10 synthesized garnet samples along the grossular-andradite binary were investigated using Raman spectroscopy. Twenty and nineteen peaks were observed in non-polarized Raman spectra for grossular and andradite end-members, respectively. The frequencies of most peaks were changed almost linearly with the composition. Two-mode behavior was not observed in this study. Differing from previous reports on other garnet solid solutions, the medium frequency modes, which are assigned to internal bending vibrations, have the largest average rate of change with the composition, which may be related to structural connectivity and coupled vibrations. Due to the reduction of symmetry, extra peaks appear in the Raman spectra of garnets with intermediate compositions. Peak broadening in intermediate compositions was also observed, which is related to disordering and distortion. One-parameter Margules equation was used to describe the full width at half maximum of peaks, and a relationship with enthalpy of mixing was proposed.
- grossular-andradite,
- Raman spectroscopy,
- bending vibration,
- extra peak,
- enthalpy of mixing

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References(34)

References

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Raman Scattering of Grossular-Andradite Solid Solution

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