High Pressure Raman Spectroscopy and X-ray Diffraction of CuS<sub>2</sub>

JIANG Feng; ZHAO Huifang; XIE Yafei; JIANG Changguo; TAN Dayong; XIAO Wansheng

doi:10.11858/gywlxb.20200509

Volume 34 Issue 4

Jul 2020

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Chinese Journal of High Pressure Physics > 2020 > 34(4): 040104.

JIANG Feng, ZHAO Huifang, XIE Yafei, JIANG Changguo, TAN Dayong, XIAO Wansheng. High Pressure Raman Spectroscopy and X-ray Diffraction of CuS2[J]. Chinese Journal of High Pressure Physics, 2020, 34(4): 040104. doi: 10.11858/gywlxb.20200509

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JIANG Feng, ZHAO Huifang, XIE Yafei, JIANG Changguo, TAN Dayong, XIAO Wansheng. High Pressure Raman Spectroscopy and X-ray Diffraction of CuS₂[J]. Chinese Journal of High Pressure Physics, 2020, 34(4): 040104. doi: 10.11858/gywlxb.20200509

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High Pressure Raman Spectroscopy and X-ray Diffraction of CuS₂

doi: 10.11858/gywlxb.20200509

JIANG Feng^{1, 2, 3
,},
ZHAO Huifang^{1, 2, 3},
XIE Yafei^{1, 2, 3},
JIANG Changguo^{1, 2, 3},
TAN Dayong^{1, 2},
XIAO Wansheng^{1, 2,*
,
,}

1.
CAS Key Laboratory of Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, Guangdong, China
2.
Key Lab of Guangdong Province for Mineral Physics and Materials, Guangzhou 510640, Guangdong, China
3.
University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 17 Feb 2020
Rev Recd Date: 26 Feb 2020
Issue Publish Date: 25 Apr 2020

Abstract

Abstract

Pyrite structure CuS₂ was synthesized in diamond anvil cell at high pressures and high temperatures. Using Raman spectroscopy and synchrotron X-ray diffraction, the pyrite-type CuS₂ was found to be stable in 0－30 GPa without any phase transition. Raman spectroscopy show that all observed Raman frequencies increasemonotonously with increasing pressures. Fitting experimental pressure and volume data of X-ray diffraction with Birch-Murnaghan equation of state, gives V₀ = 193.8(5) Å³, K₀ = 99(2) GPa and K₀' = 4 (fix). The dependencies of Raman frequencies and unit-cell volumes with pressures are coincident with the results of first-principles calculation. The results of calculation properly depict that of experiments. Compared with other pyrite structure transition-metal disulfides MS₂(M = Mn, Fe, Co, Ni), the length of M—S dominates the unit-cell volume and compressibility of MS₂, and the Cu cation tends to be +2 valance in the CuS₂. This study makes up for the lack of high-pressure Raman and XRD research of CuS₂, and confirms structural stability of pyrite-type CuS₂ at high pressures and high temperatures. The results are important for comprehending the physical and chemical properties of CuS₂ and realizing the unified law of pyrite structure materials. It’s also meaningful in discussion of the valance and distribution of copper in deep Earth.
- pyrite structure,
- CuS₂,
- Raman spectroscopy,
- X-ray diffraction,
- high pressure

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References

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High Pressure Raman Spectroscopy and X-ray Diffraction of CuS₂

doi: 10.11858/gywlxb.20200509

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High Pressure Raman Spectroscopy and X-ray Diffraction of CuS2

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