Volume 33 Issue 6
Nov 2019
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HE Xuejing, KAGI Hiroyuki, QIN Shan, WU Xiang. Compressibility of FeNiP under High Pressure[J]. Chinese Journal of High Pressure Physics, 2019, 33(6): 060106. doi: 10.11858/gywlxb.20190837
Citation: HE Xuejing, KAGI Hiroyuki, QIN Shan, WU Xiang. Compressibility of FeNiP under High Pressure[J]. Chinese Journal of High Pressure Physics, 2019, 33(6): 060106. doi: 10.11858/gywlxb.20190837

Compressibility of FeNiP under High Pressure

doi: 10.11858/gywlxb.20190837
  • Received Date: 20 Sep 2019
  • Rev Recd Date: 14 Oct 2019
  • Publish Date: 25 Oct 2019
  • Compressibility of FeNiP ($P\bar 62m$) has been studied up to 23.4 GPa by using diamond anvil cells (DAC) combined with in situ synchrotron X-ray diffraction (XRD) at room temperature. FeNiP remains the hexagonal structure at experimental pressure range. The pressure-volume (p-V) data has been fitted by the Birch-Murnaghan (B-M) equation of state, yielding K0 = 153(2) GPa, $K'_0 $ = 5.7(2), V0 = 101.6(1) Å3 or K0 = 167(1) GPa, $K'_0 $ = 4.0 (fixed), V0 = 101.5(1) Å3. FeNiP has smaller bulk modulus than Fe2P, and shows analogous axial compressibility to Ni2P. This might result from nickel’s doping effect on elastic properties of (Fe,Ni)2P. The densities of FeNiP, Fe2P, Fe3P, Fe2.15Ni0.85P and Fe3S have been estimated under the pressure-temperature conditions commensurate to the Moon’s outer core. The comparison shows that the doping of nickel could make (Fe,Ni)2P and (Fe,Ni)3P’s density approaching that of the Moon’s outer core.

     

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