Synthesis of Pure Bulk Fe<sub>3</sub>C under High Temperature and High Pressure

YANG Jun; YANG Gang; CHEN Xing; ZHAO Bin; LENG Chunwei; LIU Xun; HUANG Haijun

doi:10.11858/gywlxb.20190715

Volume 33 Issue 4

Jul 2019

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Chinese Journal of High Pressure Physics > 2019 > 33(4): 043302.

YANG Jun, YANG Gang, CHEN Xing, ZHAO Bin, LENG Chunwei, LIU Xun, HUANG Haijun. Synthesis of Pure Bulk Fe3C under High Temperature and High Pressure[J]. Chinese Journal of High Pressure Physics, 2019, 33(4): 043302. doi: 10.11858/gywlxb.20190715

Citation:

YANG Jun, YANG Gang, CHEN Xing, ZHAO Bin, LENG Chunwei, LIU Xun, HUANG Haijun. Synthesis of Pure Bulk Fe₃C under High Temperature and High Pressure[J]. Chinese Journal of High Pressure Physics, 2019, 33(4): 043302. doi: 10.11858/gywlxb.20190715

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Synthesis of Pure Bulk Fe₃C under High Temperature and High Pressure

doi: 10.11858/gywlxb.20190715

School of Science, Wuhan University of Technology, Wuhan 430070, China

Received Date: 18 Jan 2019
Rev Recd Date: 26 Mar 2019

Abstract

Abstract

Fe₃C (cementite) is a widely used material with excellent mechanical and magnetic properties; therefore the preparation method of Fe₃C has been widely concerned. In this paper, dense and high-purity bulk Fe₃C samples were prepared based on the solid-phase reaction of iron and carbon under high temperature and high pressure, and the influence of raw material type, particle size, sintering temperature, pressure, and holding time are investigated for the sintered samples. It shows that the densest samples were produced under the sintering pressure and temperature of 4 GPa and 1000 ̊C when the Fe and graphite particles were 9 ${\text{μ}}{\rm{m}}$ and 1.3 ${\text{μ}}{\rm{m}}$ respectively.
- Fe₃C,
- cubic anvil press,
- high temperature and high pressure,
- sintering

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References

[1]	蔡红, 卢军, 王志明. 渗碳体的结构和一次渗碳体形态的研究 [J]. 热处理, 2010, 25(2): 50–53. doi: 10.3969/j.issn.1008-1690.2010.02.011 CAI H, LU J, WANG Z M. Study on the structure of cementite and the morphology of primary cementite [J]. Heat Treatment, 2010, 25(2): 50–53. doi: 10.3969/j.issn.1008-1690.2010.02.011
[2]	何强. 氧化物添加剂对两步法制备碳化铁的影响[D]. 武汉: 武汉科技大学, 2008: 3–5. HE Q. Effect of oxide additives on preparation of iron carbide by two-step process [D]. Wuhan: Wuhan University of Science and Technology, 2008: 3–5.
[3]	DAVID B, SCHNEEWEISS O, PIZÚROVÁ N, et al. Nanopowders with superparamagnetic Fe₃C particles and their annealing behaviour [J]. Surface and Interface Analysis, 2010, 42(6/7): 699–702.
[4]	TERADA M, ITOH M, LIU J R, et al. Electromagnetic wave absorption properties of Fe₃C/carbon nanocomposites prepared by a CVD method [J]. Journal of Magnetism and Magnetic Materials, 2009, 321(9): 1209–1213. doi: 10.1016/j.jmmm.2008.11.001
[5]	LIPERT K, KAZMIERCZAK J, PEŁECH I, et al. Magnetic properties of cementite (Fe₃C) nanoparticle agglomerates in a carbon matrix [J]. Materials Science-Poland, 2007, 25(2): 399–404.
[6]	PRESCHER C, DUBROVINSKY L, BYKOVA E, et al. High Poisson’s ratio of Earth’s inner core explained by carbon alloying [J]. Nature Geoscience, 2015, 8(3): 220–223. doi: 10.1038/ngeo2370
[7]	WEERASINGHE G L, NEEDS R J, PICKARD C J. Computational searches for iron carbide in the Earth’s inner core [J]. Physical Review B, 2011, 84(17): 174110. doi: 10.1103/PhysRevB.84.174110
[8]	DODD S P, SAUNDERS G A, CANKURTARAN M, et al. Ultrasonic study of the temperature and hydrostatic-pressure dependences of the elastic properties of polycrystalline cementite (Fe₃C) [J]. Physica Status Solidi (A), 2003, 198(2): 272–281. doi: 10.1002/(ISSN)1521-396X
[9]	DAVID B, ZBORIL R, MASHLAN M, et al. Single ferromagnetic behaviour of nanopowders with Fe₃C [J]. Journal of Magnetism and Magnetic Materials, 2006, 304(2): e787–e789. doi: 10.1016/j.jmmm.2006.02.224
[10]	KOMOGORTSEV S V, ISKHAKOV R S, BALAEV A D, et al. Magnetic properties of Fe₃C ferromagnetic nanoparticles encapsulated in carbon nanotubes [J]. Physics of the Solid State, 2007, 49(4): 734–738. doi: 10.1134/S1063783407040233
[11]	YANG K Y, XU W, ZHANG Y, et al. Synthesis and characteristics of Fe₃C nanoparticles embedded in amorphous carbon matrix [J]. Chemical Research in Chinese Universities, 2010, 26(3): 348–351.
[12]	GAO L. Density, magnetic properties and sound velocities of iron-rich materials at high temperature and high pressure [D]. University of Illinois at Urbana-Champaign, 2011.
[13]	STEWART A J. Planetary cores: effect and behaviour of minor elements on the Fe-S system to 40 GPa [D]. Switzerland: ETH Zurich, 2006: 1–4.
[14]	DASGUPTA R, WALKER D. Carbon solubility in core melts in a shallow magma ocean environment and distribution of carbon between the Earth’s core and the mantle [J]. Geochimica et Cosmochimica Acta, 2008, 72(18): 4627–4641. doi: 10.1016/j.gca.2008.06.023

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Synthesis of Pure Bulk Fe₃C under High Temperature and High Pressure

doi: 10.11858/gywlxb.20190715

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Synthesis of Pure Bulk Fe₃C under High Temperature and High Pressure