Synthesis of Hard Superconductive Ternary Transition Metal Carbide under High Pressure and High Temperature

GAO Hao'an; MA Shuailing; BAO Kuo; ZHU Pinwen; CUI Tian

doi:10.11858/gywlxb.20170633

Volume 32 Issue 2

Jan 2018

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Chinese Journal of High Pressure Physics > 2018 > 32(2): 023301.

GAO Hao'an, MA Shuailing, BAO Kuo, ZHU Pinwen, CUI Tian. Synthesis of Hard Superconductive Ternary Transition Metal Carbide under High Pressure and High Temperature[J]. Chinese Journal of High Pressure Physics, 2018, 32(2): 023301. doi: 10.11858/gywlxb.20170633

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GAO Hao'an, MA Shuailing, BAO Kuo, ZHU Pinwen, CUI Tian. Synthesis of Hard Superconductive Ternary Transition Metal Carbide under High Pressure and High Temperature[J]. Chinese Journal of High Pressure Physics, 2018, 32(2): 023301. doi: 10.11858/gywlxb.20170633

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Synthesis of Hard Superconductive Ternary Transition Metal Carbide under High Pressure and High Temperature

doi: 10.11858/gywlxb.20170633

GAO Hao'an^{1, 2
,},
MA Shuailing¹,
BAO Kuo^{1,*
,
,},
ZHU Pinwen¹,
CUI Tian¹

1.
State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun130012, China
2.
High School Attached to Northeast Normal University, Changchun130021, China

Received Date: 21 Aug 2017
Rev Recd Date: 03 Sep 2017

Abstract

Abstract

In the present work MoWC₂ was successfully fabricated under 5.0GPa/2000K with a holding time of 60min using, as the synthetic raw material, molybdenum, tungsten and graphite powder (whose purity are more than 99.8%).Then the physical properties of the synthesized samples were characterized using X-ray diffraction, scanning electron microscopy, transmission electron microscopy, micro-hardness test, physical property measurement system and thermo gravimetric-differential thermal analyzer (TG-DTA).The results show that the MoWC₂ crystal thus synthesized has a hexagonal structure with a space group of P6-m2.It is highly crystalline with an average grain size of 1-4μm.Its convergence hardness value, oxidation temperature and the superconducting temperature are 15.3GPa, 450℃ and 6.8K, respectively.In addition, this MoWC₂ has a high hardness and oxidation resistance owing to its strong orbital hybridization.Furthermore, it is a superconducting material with a relatively high transition temperature since it has a higher density of states at the Fermi surface and Debye temperature, thereby making it a versatile material that is superconductive, highly heat-resistant, and superhard.
- high pressure and high temperature,
- transition metal carbide,
- superconductivity,
- Vickers hardness,
- oxidation resistance

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References

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Synthesis of Hard Superconductive Ternary Transition Metal Carbide under High Pressure and High Temperature

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