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Chinese Journal of High Pressure Physics  > 2018  >  32(1): 010102.
SUN Ying, ZHONG Xin, LÜ Jian, MA Yanming. Pressure-Induced Metallization and Novel Superconductivity of Chalcogen Hydrides[J]. Chinese Journal of High Pressure Physics, 2018, 32(1): 010102. doi: 10.11858/gywlxb.20170629
Citation: SUN Ying, ZHONG Xin, LÜ Jian, MA Yanming. Pressure-Induced Metallization and Novel Superconductivity of Chalcogen Hydrides[J]. Chinese Journal of High Pressure Physics, 2018, 32(1): 010102. doi: 10.11858/gywlxb.20170629
shu

Pressure-Induced Metallization and Novel Superconductivity of Chalcogen Hydrides

doi: 10.11858/gywlxb.20170629
  • 1.

    State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, China

  • 2.

    Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Siping 136000, China

  • Received Date: 11 Aug 2017
  • Rev Recd Date: 01 Sep 2017
    Abstract
  • Owing to their expected capability to reach metallization within the pressure range under the present laboratory conditions, hydrogen-rich compounds are considered promising candidates for potential high-Tc (superconductor critical temperature) superconductors.Both experimental and theoretical research have found that the critical high-temperature superconductivity can reach a record high-Tc as up to 203 K in compressed sulfur hydrides, thereby generating a new wave for searching for new hydrogen-rich superconductors.The present review focuses on researches of pressure-induced metallization and novel superconductivity in chalcogen hydrides, and discusses their differences in structures and various physical and chemical properties.Chalcogen atoms are isoelectronic but differ a lot in atomic mass and electronegativity, resulting in their great differences in stoichiometry, structure, and chemical bonding.The high-Tc superconductivity of Te/Po-H compounds originates from the strong electron-phonon couplings associated with the intermediate frequency of H-derived wagging and bending modes, a superconducting mechanism which differs substantially from those in S/Se-H compounds where the high frequency H-stretching vibrations make considerable contributions.

     

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