尼龙6在高压退火中的晶体生长

徐伟杰; 曹大呼; 俞强

doi:10.11858/gywlxb.2012.06.017

尼龙6在高压退火中的晶体生长

doi: 10.11858/gywlxb.2012.06.017

1.
常州大学材料科学与工程学院，江苏常州 213164；
2.
常州高分子材料重点实验室，江苏常州 213164

详细信息

通讯作者:
曹大呼 E-mail:dhcao2003@sohu.com

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出版历程
- 收稿日期: 2011-02-17
- 修回日期: 2011-09-13
- 发布日期: 2012-12-15

Crystal Growth of Nylon 6 by High Pressure Annealing

1.
School of Materials Science and Engineering, Changzhou University, Changzhou 213164, China;
2.
Changzhou Key Laboratory for Polymer Materials, Changzhou 213164, China

摘要

摘要: 利用六面顶压机制备了高压退火的尼龙6样品，通过宽角X射线衍射（WAXD）、差示扫描量热（DSC）和红外光谱等手段，探索了高压退火对尼龙6结晶度以及晶体结构的变化。研究发现，在高压退火过程中尼龙6分子链段运动受到压力的限制，材料中晶体的形成主要依靠转氨基反应实现。
- 高压结晶 /
- 伸直链晶体 /
- 尼龙6 /
- 高压退火
Abstract: Using a cubic-anvil high pressure apparatus, Nylon 6 samples were annealed under different pressures. The crystallinity and crystal structure changes of Nylon 6 were studied by the methods of wide-angle X-ray diffraction (WAXD), differential scanning calorimetry (DSC) and infrared spectra. The results showed that the adjustment of nylon 6 molecular chains was suppressed because of the pressure loading, and the formation of the crystals was mainly realized by the reaction of transamidation.
- high pressure crystallization /
- extended-chain crystals /
- Nylon 6 /
- high pressure annealing

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参考文献(18)

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