尼龙6在高压退火中的晶体生长

徐伟杰; 曹大呼; 俞强

doi:10.11858/gywlxb.2012.06.017

尼龙6在高压退火中的晶体生长

doi: 10.11858/gywlxb.2012.06.017

1.
常州大学材料科学与工程学院，江苏常州 213164；
2.
常州高分子材料重点实验室，江苏常州 213164

详细信息

通讯作者:
曹大呼 E-mail:dhcao2003@sohu.com

计量
- 文章访问数: 7475
- HTML全文浏览量: 549
- PDF下载量: 494
出版历程
- 收稿日期: 2011-02-17
- 修回日期: 2011-09-13
- 刊出日期: 2012-12-15

Crystal Growth of Nylon 6 by High Pressure Annealing

1.
School of Materials Science and Engineering, Changzhou University, Changzhou 213164, China;
2.
Changzhou Key Laboratory for Polymer Materials, Changzhou 213164, China

摘要

摘要: 利用六面顶压机制备了高压退火的尼龙6样品，通过宽角X射线衍射（WAXD）、差示扫描量热（DSC）和红外光谱等手段，探索了高压退火对尼龙6结晶度以及晶体结构的变化。研究发现，在高压退火过程中尼龙6分子链段运动受到压力的限制，材料中晶体的形成主要依靠转氨基反应实现。
- 高压结晶 /
- 伸直链晶体 /
- 尼龙6 /
- 高压退火
Abstract: Using a cubic-anvil high pressure apparatus, Nylon 6 samples were annealed under different pressures. The crystallinity and crystal structure changes of Nylon 6 were studied by the methods of wide-angle X-ray diffraction (WAXD), differential scanning calorimetry (DSC) and infrared spectra. The results showed that the adjustment of nylon 6 molecular chains was suppressed because of the pressure loading, and the formation of the crystals was mainly realized by the reaction of transamidation.
- high pressure crystallization /
- extended-chain crystals /
- Nylon 6 /
- high pressure annealing

HTML全文

参考文献(18)

Wunderlich B. The effect of pressure on the crystallization of polyethylene from dilute solution [J]. Journal of Polymer Science Part A: General Papers, 1963, 1(4): 1245-1255.

Bassett D, Block S, Piermarini G. A high-pressure phase of polyethylene and chain-extended growth [J]. J Appl Phys, 2009, 45(10): 4146-4150.

Matsushige K, Takemura T. Melting and crystallization of poly (vinylidene fluride) under high pressure [J]. J Polymer Sci: Polymer Phys Ed, 1978, 16(5): 921-934.

Siegmann A, Harget P. Melting and crystallization of poly (ethylene terephthalate) under pressure [J]. J Polymer Sci: Polymer Phys Ed, 1980, 18(11): 2181-2196.

Gogolewski S, Pennings A. Crystallization of polyamides under elevated pressure: Nylon-6 (polycapramide) [J]. Polymer, 1973, 14(9): 463-464.

Gogolewski S, Pennings A. Crystallization of polyamides under elevated pressure: (4) Annealing of Nylon-6 (polycapramide) under pressure [J]. Polymer, 1977, 18(7): 654-659.

Li P, Huang R, Huang H. A Review on the hexagonal phase of polyethylene [J]. Polymer Bulletin, 2000, (4): 34-42. (in Chinese)

李鹏, 黄锐, 黄海. 聚乙烯六方相 [J]. 高分子通报, 2000, (4): 34-42.

Gogolewski S. A possible mechanism of chain extension in Nylon-6 during crystallization under pressure [J]. Polymer, 1977, 18(1): 63-68.

Gogolewski S, Pennings A. Crystallization of polyamides under elevated pressure: (2) Pressure-induced crystallization of nylon-6 (polycapramide) from the melt [J]. Polymer, 1975, 16(9): 673-679.

Schaefgen J R, Flory P J. Synthesis of multichain polymers and investigation of their viscosities [J]. J Am Chem Soc, 1948, 70(8): 2709-2718.

Mattiussi A, Gechele G B, Francesconi R. Polyamides in solution: (Ⅲ) Viscometry of linear polycaprolactam [J]. J Polymer Sci Part A-2: Polymer Phys, 1969, 7(2): 411-422.

Arakawa T, Nagatoshi F. Melting of paracrystals [J]. J Polymer Sci Part B: Polymer Lett, 1970, (1): 41-45.

Magill J. Crystallization of polyamides. Part Ⅱ: Nylon-6 and Nylon-66 [J]. Polymer, 1965, 6: 367-371.

Arakawa T, Nagatoshi F, Arai N. Thermal analysis of drawn Nylon-6 [J]. J Polymer Sci Part B: Polymer Letts, 1968, 6(7): 513-516.

Gogolewski S, Pennings A. Crystallization of polyamides under elevated pressure: (3) The Morphology and structure of pressure-crystallized Nylon-6 (polycapramide) [J]. Polymer, 1977, 18(7): 647-653.

Li P. On the pressure cryatallization of polyethylene [D]. Chengdu: Sichuan University, 1999: 30-34. (in Chinese)

李鹏. 聚乙烯在压力下结晶 [D]. 成都: 四川大学, 1999: 30-34.

施引文献

资源附件(0)

访问统计