Influence of Detonation Velocity on Sintering Performance of Nano-Aluminum Powders
-
摘要: 为了掌握纳米金属粉烧结成型技术, 将纳米铝粉置于改良设计的可泄压式爆炸烧结装置中, 得到了密实度达98%以上的纳米铝棒。通过改变铵梯炸药和木粉的比例调节炸药的爆速, 研究了不同爆速下烧结铝棒的性能。利用金相显微镜观察烧结棒的微观结构, 并对烧结棒的密实度、硬度等性能进行测量。结果表明:通过降低爆速可以减小马赫孔的产生, 但爆速过低, 会导致烧结棒的密实度和硬度等性能降低; 当采用爆速为2 158 m/s的炸药时, 可制得无马赫孔、高硬度、高密实度、晶粒细小的均质烧结棒。Abstract: An aluminum bar with a dense degree of over 98% was fabricated using nano-aluminum powders in an improved sintering device capable of pressure relief to study the sintering molding of nanometer metal powders.First, the performance of the sintering aluminum bar at different detonation velocities were obtained by adjusting the ratio of the ammonium nitrate explosive to the wood powder.Then the microstructures of the aluminum bars were observed using metallurgical microscopy, and such mechanical properties as the density and hardness were measured.The results show that the Mach-hole can be reduced by reducing the detonation velocity.However, the excessively low detonation velocity decreases the mechanical properties such as the density and the hardness.Moreover, the sintering aluminum bar that is free from any Mach-hole, of higher hardness, higher dense degree and finer grain size can be fabricated from nano-aluminum powers whose detonation velocity reaches 2 158 m/s.
-
Key words:
- explosive sintering /
- nano-aluminum powers /
- detonation velocity /
- Mach-hole
-
表 1 爆速测试实验结果
Table 1. Experiment results of the detonation velocity
No. L/mm d/mm w/% D′/(m·s-1) 1 200 20 0 3 015 2 200 20 5.0 2 460 3 200 20 7.5 2 278 4 200 20 10.0 2 158 5 200 20 12.5 2 016 6 200 20 15.0 1 832 表 2 不同爆速下爆炸烧结铝棒的密度和密实度
Table 2. Density and dense degree of sintered aluminum bar with different explosive velocities
w/% D′/(m·s-1) ρ/(g·cm-3) Dense degree/% 7.5 2 278 2.671 98.9 10.0 2 158 2.692 99.7 12.5 2 016 2.652 98.2 -
[1] 张中太, 林元华, 唐子龙, 等.纳米材料及其技术的应用前景[J].材料工程, 2000(3):42-48. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=clgc200003012ZHANG Z T, LIN Y H, TANG Z L, et al.Nanometer materials & nano technology and their application prospect[J].Journal of Materials Engineering, 2003(3):42-48. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=clgc200003012 [2] 陈海英, 冯凤, 张飞, 等.铜纳米材料的制备、应用及安全性研究进展[J].化工新型材料, 2016(10):11-13.CHEN H Y, FENG F, ZHANG F, et al.Preparation, application, and safety of copper nanoparticle[J].New Chemical Materials, 2016(10):11-13. [3] 李晓杰, 赵铮, 曲艳东, 等.爆炸烧结制备CuCr合金[J].爆炸与冲击, 2005, 25(3):251-254. doi: 10.11883/1001-1455(2005)03-0251-04LI X J, ZHAO Z, QU Y D, et al.Producing CuCr alloy by explosive sintering[J].Explosion and Shock Waves, 2005, 25(3):251-254. doi: 10.11883/1001-1455(2005)03-0251-04 [4] HOKAMOTO K, SHIMOMIYA K, NISHI M, et al.Synthesis of unidirectional porous-structured aluminum through explosive compaction using cylindrical geometry[J].Journal of the Japan Society for Technology Plasticity, 2017, 673(58):156-160. https://www.jstage.jst.go.jp/article/sosei/58/673/58_156/_article [5] VOROZHTSOV S, VOROZHTSOV A, KUDRYASHOVA O, et al.Structural and mechanical properties of aluminium-based composites processed by explosive compaction[J].Powder Technology, 2017, 313(15):251-259. https://www.sciencedirect.com/science/article/pii/S0032591017302334 [6] 李晓杰, 王金相, 闫鸿浩.爆炸粉末烧结机理的研究现状及其发展趋势[J].稀有金属材料与工程, 2004, 33(6):566-570. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=xyjsclygc200406002LI X J, WANG J X, YAN H H.The survey and development trend of the research for the mechanism of explosive consolidation of powders[J].Rare Metal Materials and Engineering, 2004, 33(6):566-570. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=xyjsclygc200406002 [7] 刘麒峰, 赵捍东, 王金虎.W-Cu复合药型罩EFP的形成及其聚能破甲效应研究[J].兵器材料科学与工程, 2015, 38(6):102-105. http://www.cqvip.com/QK/95120X/201506/666607280.htmlLIU Q F, ZHAO H D, WANG J H.EFP formation of W-Cu double layered charge liners and its peed penetration effect[J].Ordnance Material Science and Engineering, 2015, 38(6):102-105. http://www.cqvip.com/QK/95120X/201506/666607280.html [8] VESENJAK M, HOKAMOTO K, MATSUMOTO S, et al.Uni-directional porous metal fabricated by rolling of copper sheet and explosive compaction[J].Materials Letters, 2016, 170(1):39-43. https://www.sciencedirect.com/science/article/pii/S0167577X1630146X [9] ZELEPUGIN S A, IVANOVA O V, YUNOSHEV A S, et al.Problems of solid-phase synthesis in cylindrical ampoules under explosive loading[J].IOP Conference Series:Materials Science and Engineering, 2016, 127(1):012057. doi: 10.1088/1757-899X/127/1/012057 [10] 王占磊, 王慧萍, 王岭渠, 等.爆炸压实W-Cu粉末的数值模拟与实验验证[J].稀有金属材料与工程, 2014, 43(8):1997-2001.WANG Z L, WANG H P, WANG L Q, et al.Numerical simulation of explosive compaction of W-Cu powder and experiment validation[J].Rare Metal Materials and Engineering, 2014, 43(8):1997-2001. [11] 孟松鹤, 李金平, 韩杰才.粉末的爆炸压实工艺[J].材料科学与工艺, 2006, 14(4):404-407. http://www.cqvip.com/QK/91902A/200604/22690014.htmlMENG S H, LI J P, HAN J C.Explosive compaction of powders[J].Materials Science and Technology, 2006, 14(4):404-407. http://www.cqvip.com/QK/91902A/200604/22690014.html [12] 陈代贵, 王成合.木粉、硝铵的水分、细度对铵梯炸药的殉爆和爆速的影响[J].宝鼎科技, 2003(3):22-23.CHEN D G, WANG C H.The effection of wood powder, moisture of ammonium nitrate and fineness to the sympathetic detonation and detonation velocity of the ammonium nitrate explosive[J].BAODING Technology, 2003(3):22-23. [13] 李晓杰, 王金相, 陈浩然, 等.金属粉末爆炸烧结颗粒间结合细观机制研究[J].应用基础与工程科学学报, 2005, 13(1):58-66. http://www.cqvip.com/QK/84465X/200501/15480010.htmlLI X J, WANG J X, CHEN H R, et al.Research of microcosmic bonding mechanism of particles in explosive consolidation of metal powders[J].Journal of Basic Science and Engineering, 2005, 13(1):58-66. http://www.cqvip.com/QK/84465X/200501/15480010.html [14] 李维新.一维不定常流与冲击波[M].北京:国防工业出版社, 2003:250-300.LI W X.One-dimensional nonsteady flow and shock waves[M].Beijing:National Defend Industry Press, 2003:250-300. [15] 王占磊. 爆炸压实W-Cu纳米合金及其聚能破甲应用研究[D]. 大连: 大连理工大学, 2012: 38-42.WANG Z L. Research on explosive of W-Cu nanoalloy and the application to shaped charge liner[D]. Dalian: Dalian University of Technology, 2012: 38-42.